XRF can analyze a wide range of elements, typically from sodium (11Na) to uranium (92U). X-ray fluorescence (XRF) is the emission of characteristic "secondary" (or fluorescent) X-rays from a material that has been excited by being bombarded with high-energy X-rays or gamma rays. When a material is illuminated with high-energy X-rays, its atoms can become excited and emit their own. X-ray fluorescence (XRF) is a fast, non-destructive analytical technique used to identify and quantify the elemental composition of a material. The operational principles of this system are based on.